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Beilstein J. Org. Chem. 2015, 11, 1392–1397, doi:10.3762/bjoc.11.150
Graphical Abstract
Scheme 1: Synthesis of vinyl C-deoxyribosides α-2 and β-2.
Figure 1: Alkenes 3 used in cross-metathesis reactions with 2.
Scheme 2: Hydrogenation of β-4b–β-4d to β-5b–β-5d.
Scheme 3: Deprotection of β-4e and β-5b to β-6e and β-7b.
Beilstein J. Org. Chem. 2010, 6, 1099–1105, doi:10.3762/bjoc.6.126
Figure 1: Starting allylcarboranes 1a–1c and O-allylcyclodextrins 2a–2c.
Scheme 1: Cross-metathesis of allylcarboranes 1 and O-allylcyclodextrins 2.